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CATALYSIS AND SUPRAMOLECULAR CHEMISTRY

 

Elaboration of supramolecular bidentate ligands for aqueous organometallic catalysis

 

We recently showed that the association of a monoamino β-CD and a hydrosoluble phosphine (tBuTPPDS) led to a supramolecular heterobidentate ligand able to coordinate a platinum species. This supramolecular assembly catalyses the hydrogenation of an allylic alcohol in aqueous media [P1].

 

 

Publications :

 

• P 1. First example of self-assembled supramolecular bidentate ligands for aqueous organometallic catalysis.

  C. Machut, J. Patrigeon, S. Tilloy, H. Bricout, F. Hapiot, E. Monflier,
  Angew. Chem. Int. Ed. 46 (2007) 3040-3042.

 

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