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Stéphane Menuel joined the team “Supramolecular Catalysis” of UCCS-Artois in 2007. He is a young researcher now recognized for its expertise in synthesis of modified cyclodextrins and their studies in supramolecular chemistry and in aqueous catalysis. His current research is focused on design and characterization of supramolecular systems based on cyclodextrins for molecular recognition and biphasic catalysis. He has played a key role in the development of new supramolecular hydrogels for catalysis applications notably by the discovery of Pickering emulsion effect in the new reaction medium for the hydroformylation of very hydrophobic alkenes. His current work deals with supramolecular catalysis and unusual reaction medium for the development of Green Chemistry.

Lien Conférence Année de la chimie 2018-2019 - conférence donnée le 11 octobre 2018 :

La Chimie Verte : "Influence de la chimie sur l'environnement : du constat à l'action !" - WebTV Artois

Par Stéphane Menuel

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Publications 2024:

  1. «Mechanochemical synthesis of β-cyclodextrin urea derivatives under reactive CO2 atmosphere by Staudinger aza-Wittig reaction»
    S. Nasri, M. Lestoquoy, A. Ponchel, E. Monflier, S. Menuel
    RSC Mechanochemistry, 2024, 1, 228-234     - doi: 10.1039/D4MR00020J
    [With cover]

Publications 2021:

  1. «Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin»
    S. Noël, E. Caronia, H. Bricout, I. Chena Tichá, S. Menuel, A. Ponchel, S. Tilloy, A. Galia, E. Monflier, J. Jindřich, B. Léger
    Catal. Commun. 2021, 150, 106272     - doi: 10.1016/j.catcom.2020.106272

Publications 2020:

  1. «Particle size effect in the mechanically assisted synthesis of β-cyclodextrin mesitylene sulfonate»
    S. Menuel, S. Saitzek, E. Monflier, F. Hapiot
    Beilstein Journal of Organic Chemistry, 2020, 16, 2598-2606     - doi: 10.3762/bjoc.16.211

Publications 2019:

  1. «Hydrogenation of hydrophobic substrates catalyzed by gold nanoparticles embedded in Tetronic/cyclodextrin-based hydrogels»
    M. Chevry, S. Menuel, B. Léger, S. Noël, E. Monflier, F. Hapiot
    New. J. Chem. 2019, 43, 9865-9872     - doi: 10.1039/c8nj06081a

Publications 2018:

  1. «Pillar[5]arenes as supramolecular hosts in aqueous biphasic rhodium-catalyzed hydroformylation of long alkyl-chain alkenes»
    M. Benatmane, K. Cousin, N. Laggoune, S. Menuel, E. Monflier, P. Woisel, F. Hapiot, J. Potier
    ChemCatChem, 2018, 10, 5306-5313     - doi: 10.1002/cctc.201801551

Publications 2017:

  1. «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
    J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
    Catal. Sci. Technol. 2017, 7, 3823 – 3830     - doi: 10.1039/C7CY01108C
    See «Publications marquantes 2017»

  2. «Hydroformylation of alkenes in a planetary ball mill: from additive-controlled reactivity to supramolecular control of regioselectivity»
    K. Cousin, S. Menuel, E. Monflier, F. Hapiot
    Angew. Chem. Int. Ed. 2017, 56, 10564-10568     - doi: 10.1002/anie.201705467
    See «Publications marquantes 2017»

  3. «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
    F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
    ACS Sustainable Chem. Eng. 2017, 5, 3598-3606     - doi: 10.1021/acssuschemeng.6b02886
    See «Publications marquantes 2017»

  4. «Tetronics/cyclodextrin-based hydrogels as catalyst-containing media for the hydroformylation of higher olefins»
    M. Chevry, T. Vanbesien, S. Menuel, E. Monflier, F Hapiot
    Catal. Sci. Technol., 2017, 7, 114-123     - doi: 10.1039/C6CY02070D
    See «Publications marquantes 2017»

Publications 2016 :

  1. «Active hydrogenation Rh nanocatalysts protected by new self-assembled supramolecular complexes of cyclodextrins and surfactants in water»
    N.T.T. Chau, S. Menuel, S. Colombel-Rouen, M. Guerrero, E. Monflier, K. Philippot, A. Denicourt-Nowicki, A. Roucoux
    RSC Adv. 2016, 6, 108125-108131     - doi: 10.1039/C6RA21851B

  2. «Cyclodextrins as Effective Additives in AuNPs-Catalyzed Reduction of Nitrobenzene Derivatives in a Ball-Mill»
    S. Menuel, B. Léger, A. Addad, E. Monflier, F. Hapiot
    Green Chem. 2016, 18, 5500–5509     - doi: 10.1039/C6GC00770H
    See «Publications marquantes 2016»

  3. «Greener Paal-Knorr pyrrole synthesis by mechanical activation»
    L. Akelis, J. Rousseau, R. Juskenas, J. Dodonova, C. Rousseau, S. Menuel, D. Prevost, S. Tumkevičius, E. Monflier, F. Hapiot
    Eur. J. Org. Chem. 2016, 31-35     - doi: 10.1002/ejoc.201501223

  4. «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
    S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
    Current Organocatalysis volume 3, pages 24-31, 2016
    doi: 10.2174/2213337202666150618192947

Publications 2015:

  1. «Cyclodextrin-based PNN supramolecular assemblies: a new class of pincer-type ligands for aqueous organometallic catalysis»
    S. Menuel, E. Bertaut, E. Monflier, F. Hapiot
    Dalton Trans. 2015, 44, 13504–13512
    HOT article         - doi: 10.1039/C5DT01825K

  2. «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
    F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
    Appl. Organometal. Chem. 2015, 29, 580–587     - doi: 10.1002/aoc.3340

  3. «Selective secondary face modification of cyclodextrins by mechanosynthesis»
    S. Menuel, B. Doumert,; S. Saitzek, A. Ponchel, L. Delevoye, E. Monflier, F. Hapiot
    J. Org. Chem. 2015, 80, 6259-6266     - doi: 10.1021/acs.joc.5b00697

  4. «Ruthenium-containing β-cyclodextrin polymer globules for the catalytic hydrogenation of biomass-derived furanic compounds»
    R. Herbois, S. Noël, B. Léger, S. Tilloy, S. Menuel, A. Addad, B. Martel, A. Ponchel, E. Monflier
    Green Chem. 2015, 17, 2444 - 2454     - doi: 10.1039/C5GC00005J
    See «Publications marquantes 2015»

  5. «Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation»
    J. Potier, A. Guerriero, S. Menuel, E. Monflier, Peruzzini, F. Hapiot, L. Gonsalvi
    Catal. Com. 2015, 63, 74-78     - doi: 10.1016/j.catcom.2014.11.030

  6. «Rhodium Catalyzed Hydroformylation of 1-Decene in Low Melting Mixtures Based on Various Cyclodextrins and N,N’-Dimethylurea»
    M. Ferreira, F. Jérôme, H. Bricout, S. Menuel, D. Landy, S. Fourmentin, S. Tilloy, E. Monflier
    Catal. Com., 2015, 63, 62-65 -     doi : 10.1016/j.catcom.2014.11.001

  7. «Thermoresponsive self-assembled cyclodextrin-end-decorated PNIPAM for aqueous catalysis»
    J. Potier, S. Menuel, J. Lyskawa, D.Fournier, F. Stoffelbach, E. Monflier, P. Woisel, F. Hapiot
    Chem. Commun., 2015, 51, 2328-2330     - doi: 10.1039/c4cc09052g
    See «Publications marquantes 2015»

Publications 2014:

  1. «Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis»
    J. Potier, S. Menuel, D. Mathiron, V. Bonnet, F. Hapiot, E. Monflier
    Beilstein J. Org. Chem. 2014, 10, 2642-2648     -.doi: 10.3762/bjoc.10.276

  2. «Low melting mixtures based on β-cyclodextrin derivatives and N,N’-dimethylurea as solvents for sustainable catalytic processes»
    F. Jerome, M. Ferreira, H. Bricout, S. Menuel, E. Monflier, S. Tilloy
    Green Chem., 2014, 16 (8), 3876 - 3880     - doi: 10.1039/C4GC00591K
    See «Publications marquantes 2014»

  3. «Access to Pyrrole in Water by Methylated Cyclodextrins Assistance»
    S. Menuel, J. Rousseau, C. Rousseau, E. Vaičiūnaite, J. Dodonova, S.Tumkevičius, E. Monflier
    Eur. J. Org. Chem., 2014 -4356-4361     - doi: 10.1002/ejoc.201402327

  4. «Synergetic effect of randomly methylated ß-cyclodextrin and supramolecular hydrogel in Rh-catalyzed hydroformylation of higher olefins»
    J. Potier, S. Menuel, E. Monflier, F. Hapiot
    ACS Catalysis 2014, 4, 2342-2346     - doi: 10.1021/cs5004883
    See «Publications marquantes 2014»

  5. «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
    F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
    Catal. Sci. Technol., 2014, 4, 1899-1908     - doi: 10.1039/C4CY00005F

  6. «Multifunctional cyclodextrin-based N,N-bidentate ligands for aqueous Heck arylation»
    J.Potier, S.Menuel, J.Rousseau, S.Tumkevicius, F.Hapiot, E.Monflier
    Applied Catalysis A:General, 2014, 479, 1-8     - doi: 10.1016/j.apcata.2014.04.021

  7. «Limits of the Inversion Phenomenon in Triazolyl-Substituted β-Cyclodextrin Dimers»
    J. Potier, S. Menuel, N. Azaroual, E. Monflier, F. Hapiot
    Eur. J. Org. Chem. 2014 -1547-1556     - doi: 10.1002/ejoc.201301681

  8. «Evidence for the existence of crosslinked crystalline domains within cyclodextrin-based supramolecular hydrogels through sol-gel replication»
    R. Bleta, S. Menuel, B. Léger, A. Da Costa, E. Monflier, A. Ponchel
    RSC Adv., 2014, 4 (16), 8200 - 8208     - doi: 10.1039/c3ra47765g

  9. «Base directed palladium catalyzed Heck arylation of acrolein diethyl acetal in water»
    W. Al-Maksoud, S. Menuel, M. Jahjah, E. Monflier, C. Pinel, L. Djakovitch
    Appl. Catal. A Gen., 2014, 469 (2014) 250 – 258     - doi: 10.1016/j.apcata.2013.10.004

 

 

 
 

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