
Hervé Bricout
was born in Maubeuge (France) in 1969. He received his Ph.D.
degree from the University of Lille I in 1997
under the supervision of Professor A.
Mortreux. During his Ph.D., he studied the catalytic
properties of homogeneous nickel complexes in isomerization
and substitution reactions of allylic compounds.
Then, he reached the L.P.C.I.A.,
in the research group directed by Professor
Eric Monflier, and became «Maître de Conférences »
in 1997.
His work in this group deals with biphasic catalysis mediated
by metal complexes modified by watersoluble
phosphanes, and assisted by
cyclodextrins as polyvalent
promoters : mass transfer
and substrate selectivity enhancement
agents but also host
molecules able to generate specific catalytic species.
orcid.org/0000-0002-4895-1636
Publications 2025:
- «Non-Classical Nitrogen Promoters for Rhodium-Catalyzed Reductive Hydroformylation: New EfficientWay to Access Polyols From Linseed Oil»
W. Abdallah, M. Ferreira, S. Laclef, D. Mathiron, S. Pilard, R. Froidevaux, M. De Sousa Lopes Moreira, H. Bricout, E. Monflier, S. Tilloy
European Journal of Lipid Science and Technology, 2025; 0:e70021 - doi: 10.1002/ejlt.70021
- «Rhodium/Trialkylamines Catalyzed Reductive Hydroformylation in Ionic Liquid/Heptane Medium: An Unexpected Concept for Catalyst Recycling in Batch and Continuous Flow Processes»
A. El Mouat, W. Abdallah, J. Ternel, M. Ferreira, H. Bricout, A.J. Vorholt, H. Stieber, S. Stoertte, E. Monflier, M. Lahcini, S. Tilloy
ChemSusChem 2025, e202401384 - doi: 10.1002/cssc.202401384
Publications 2024:
- «Aqueous biphasic hydroformylation and hydroaminomethylation assisted by cyclodextrins: From benchtop to industrial perspective»
M. Ferreira, H. Bricout, T.F.H. Roth, T. Seidensticker, S. Tilloy, E. Monflier
Catal. Today 2024, 442, 114951 - doi: 10.1016/j.cattod.2024.114951
- «Rhodium-Catalyzed Reductive Hydroformylation of Polyunsaturated Vegetable Oils Assisted by Triethylamine/N-methylimidazole Ligands Combination»
W. Abdallah, M. Ferreira, C. Becquet, J. Ternel, H. Bricout, E. Monflier, S. Tilloy
ChemCatChem 2024, 0, e202401677 - doi: 10.1002/cctc.202401677
Publications 2023:
- «Exploiting poly(ε-caprolactone) grafted from hydrohydroxymethylated sunflower oil as biodegradable coating material of water-soluble fertilizers»
A. El Mouat, T. El Assimi, M. Raihane, J. Ternel, H. Bricout, E. Monflier, S. Tilloy, M. Lahcini
Progress in Organic Coatings 179 (2023) 107513 - doi: 10.1016/j.porgcoat.2023.107513
Publications 2022:
- «Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes»
C. Becquet, M. Ferreira, H. Bricout, B. Quienne, S. Caillol, E. Monflier and S. Tilloy
Green Chemistry, 2022, 24, 7906–7912 - doi: 10.1039/D2GC02534E
- «Promising Recyclable Ionic Liquid-Soluble Catalytic System for Reductive Hydroformylation»
A. El Mouat, C. Becquet, J. Ternel, M. Ferreira, H. Bricout, E. Monflier, M. Lahcini, and S. Tilloy
ACS Sustainable Chem. Eng, 10, 34, 11310–11319 - doi : 10.1021/acssuschemeng.2c03302
Publications 2021:- «Reductive Hydroformylation of Isosorbide Diallyl Ether»
J. Ternel, A. Lopes, M. Sauthier, C. Buffe, V. Wiatz, H. Bricout, S. Tilloy, and E. Monflier Molecules, 2021, 26, 7322 - doi: 10.3390/molecules26237322
- «Hydrohydroxymethylation of Ethyl Ricinoleate and Castor Oil»
C. Becquet, F. Berche, H. Bricout, E. Monflier, S. Tilloy
ACS Sustain Chem Eng, 2021, 9, 9444−9454 -
doi: 10.1021/acssuschemeng.1c02924
- «Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin»
S. Noël, E. Caronia, H. Bricout, I. Chena Tichá, S. Menuel, A. Ponchel, S. Tilloy, A. Galia, E. Monflier, J. Jindřich, B. Léger
Catal. Commun. 2021, 150, 106272 - doi: 10.1016/j.catcom.2020.106272
- «Epimerization of Isosorbide Catalyzed by Homogeneous Ruthenium-Phosphine Complexes: a New Step towards an Industrial Process»
T. Vanbésien, T. Delaunay, V. Wiatz, S. Bigot, H. Bricout, S. Tilloy, E. Monflier
Inorg. Chim. Acta 2021, 515, 120094 - doi: 10.1016/j.ica.2020.120094
Publications 2020: - «Catalytic reduction of 4-nitrophenol with gold nanoparticles stabilized by large-ring cyclodextrins»
S. Noel, H. Bricout, A. Addad, C. Sonnendecker, W. Zimmermann, E. Monflier, B. Leger
New J. Chem. 2020, 44, 21007-21011 - doi: 10.1039/D0NJ03687K
- «Anionic Amphiphilic Cyclodextrins bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation»
A. Cocq, B. Léger; S. Noel; H. Bricout; F. Pilard; S. Tilloy; E. Monflier
ChemCatChem 2020, 12, 1013-1018 - doi: 10.1002/cctc.201901837
- «Multiscale Structure of Starches Grafted with Hydrophobic Groups: A new Analytical Strategy»
C. Volant, A. Gilet, F. Beddiaf, M. Collinet-Fressancourt, X. Falourd, N. Descamps, V. Wiatz, H. Bricout, S. Tilloy, E. Monflier, C. Quettier, A. Mazzah, A. Rolland-Sabate
Molecules 2020, 25, 2827 - doi:10.3390/molecules25122827
- «New Lipidyl-Cyclodextrins Obtained by Ring Opening of Methyl Oleate Epoxide Using Ball Milling»
E. Oliva, D. Mathiron, S. Rigaud, E. Monflier, E. Sevin, H. Bricout, S. Tilloy, F. Gosselet, L. Fenart, V. Bonnet, S. Pilard and F. Djedaini-Pilard
Biomolecules, 2020, 10(2), 339 - doi: 10.3390/biom10020339
- «Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins»
A. Cocq, H. Bricout, F. Djedaïni-Pilard, S. Tilloy, E. Monflier
Catalysts 2020, 10, 56 - doi: 10.3390/catal10010056
Publications 2019:
- «Highly Water-Soluble Amphiphilic Cyclodextrins bearing Branched and Cyclic Oleic Grafts»
A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
Eur. J. Org. Chem. 2019, 4863-4868 - doi : 10.1002/ejoc.201900789
- «First evidence of cyclodextrin inclusion complexes in a deep eutectic solvent»
T. Moufawad, L. Moura, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M. Costa Gomes, D. Landy, S. Fourmentin
ACS SUSTAIN CHEM ENG, 2019, 7, 6, 6345–6351 - doi: 10.1021/acssuschemeng.9b00044
- «Synthesis of 2-Hydroxydodecyl Starch Ethers: Importance of the Purification Process»
A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier, and S. Tilloy
Ind. Eng. Chem. Res. 2019, 58, 7, 2437-2444 - doi: 10.1021/acs.iecr.8b02605
- «Oleic Acid Based Cyclodextrins for the Development of New Hydrosoluble Amphiphilic Compounds»
A. Cocq, C. Rousseau, H. Bricout, E. Oliva, V. Bonnet, F. Djedaini-Pilard, E. Monflier, S. Tilloy
Eur. J. Org. Chem. 2019 , 1236–1241 - doi: 10.1002/ejoc.201801609
Publications 2018:- «New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction»
M. Dauchy, M. Ferreira, J. Leblond, H. Bricout, S. Tilloy, G. S. Smith, E. Monflier
Pure Appl. Chem., 2018, 90(5), 845-855 -. doi: 10.1515/pac-2017-1205
- «Unconventional media and technologies for starch etherification and esterification»
A. Gilet, C. Quettier, V. Wiatz, H. Bricout, M. Ferreira, C. Rousseau, E. Monflier and S. Tilloy
Green Chem., 2018, 20, 1152–1168 - doi: 10.1039/C7GC03135A
Publications 2017:- «Deep eutectic solvents: a promising medium for Volatile Organic Compounds absorption»
L. Moura, T. Moufawad, M. Ferreira, H. Bricout, S. Tilloy, E. Monflier, M.F. Costa Gomes, D. Landy, S. Fourmentin
Environ. Chem. Lett. 2017, 15(4), 747-753 - doi: 10.1007/s10311-017-0654-y
- «Polyoxometalate, cationic cluster and g-cyclodextrin. From primary interactions to supramolecular hybrid materials»
M. Aly Moussawi, N. Leclerc, P. Abramov, M.N. Sokolov, S. Cordier, A. Ponchel, E. Monflier, H. Bricout, D. Landy, M. Haouas, J. Marrot, E. Cadot
J Am Chem Soc 2017, 139, 12793-12803 - doi: 10.1021/jacs.7b07317
- «Water-soluble Phosphane-Substituted Cyclodextrin as Effective Bifunctional Additive in Hydroformylation of Higher Olefins»
J. Leblond, J. Potier, S. Menuel, H. Bricout, C. Machut-Binkowski, D. Landy, S. Tilloy, E. Monflier, F. Hapiot
Catal. Sci. Technol. 2017, 7, 3823 – 3830 - doi: 10.1039/C7CY01108C
- «Green and scalable palladium on carbon-catalyzed Tsuji-Trost coupling reaction using an efficient and continuous flow system»
C. Cazorla, M. Billamboz, H. Bricout, E. Monflier, C. Len
Eur. J. Org. Chem., 2017, 1078-1085 - doi: 10.1002/ejoc.201601311
- «Catalysis in cyclodextrin-based unconventional reaction media: recent developments and future opportunities»
F. Hapiot, S. Menuel, M. Ferreira, B. Léger, H. Bricout, S. Tilloy, E. Monflier
ACS Sustainable Chem. Eng. 2017, 5, 3598-3606 - doi: 10.1021/acssuschemeng.6b02886
- «Transition metal complexes coordinated by water soluble phosphane ligands: How cyclodextrins can alter the coordination Sphere?»
M. Ferreira, H. Bricout, S. Tilloy, E. Monflier
Molecules 2017, 22, 140 - doi: 10.3390/molecules22010140
Publications 2016:
- «Cleavage of Benzyl Phosphonium Salts as Efficient Bypass for Synthesis of Disulfonated Alkyldiphenylphosphanes Bearing an Oleum-Sensitive Alkyl Group»
J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
Eur. J. Org. Chem. 2016, 3322–3325 - doi: 10.1002/ejoc.201600555
- «Methylated β-cyclodextrins decrease cholesterol release in smooth muscle cells and aortic endothelial cells via ABCA1- and ABCG1-mediated process»
C. Coisne, D. Hallier-Vanuxeem, M-C. Boucau, J. Hachani, S. Tilloy, H. Bricout, E. Monflier, D. Wils, M. Serpelloni, X. Parissaux, L. Fenart, F. Gosselet
Frontiers in Physiology, section Lipidology, 2016, 7, 185 - doi: 10.3389/fphys.2016.00185
- «Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What remains to be done?»
S. Tilloy, H. Bricout, S. Menuel, F. Hapiot and E. Monflier
Current Organocatalysis volume 3, pages 24-31, 2016
doi: 10.2174/2213337202666150618192947
Publications 2015:
- «Tetrasulfonated 1,2-Bis(diphenylphosphanyl)ethane as a Building Block for the Synthesis of Disulfonated Alkyldiphenylphosphanes»
J. Denis, M. Ferreira, H. Bricout, C. Machut, S. Tilloy, E. Monflier
Eur. J. Org. Chem 2015, 5509–5512 - doi: 10.1002/ejoc.201500772
- «Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and Tsuji-Trost reactions»
F. Hapiot, S. Menuel, H. Bricout, S. Tilloy, E. Monflier
Appl. Organometal. Chem. 2015, 29, 580–587 - doi: 10.1002/aoc.3340
- «Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands»
K. Sordakis, A. Guerriero, H. Bricout, M. Peruzzini, P. J. Dyson, E. Monflier, F. Hapiot, L. Gonsalvi, G. Laurenczy
Inorganica Chimica Acta 2015, 431, 132–138
- doi: 10.1016/j.ica.2014.10.034
- «Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?»
M. Elard, J. Denis, M. Ferreira, H. Bricout, D. Landy, S. Tilloy, E. Monflier
Catalysis Today 247 (2015) 47–54 - doi: 10.1016/j.cattod.2014.06.002
- «Rhodium Catalyzed Hydroformylation of 1-Decene in Low Melting Mixtures Based on Various Cyclodextrins and N,N’-Dimethylurea»
M. Ferreira, F. Jérôme, H. Bricout, S. Menuel, D. Landy, S. Fourmentin, S. Tilloy, E. Monflier
Catal. Com., 2015, 63, 62-65 - doi : 10.1016/j.catcom.2014.11.001
Publications 2014: - «Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer»
F. Hamon, C. Blaszkiewicz, M. Buchotte, E. Banaszak-Léonard, H. Bricout, S. Tilloy, E. Monflier, C. Cézard, L. Bouteiller, C. Len and F. Djedaini-Pilard
Beilstein J. Org. Chem. 2014, 10, 2874–2885 - doi: 10.3762/bjoc.10.304
- «Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution»
A. Guerriero, H. Bricout, K. Sordakis, M. Peruzzini, E. Monflier, F. Hapiot, G. Laurenczy, L. Gonsalvi
ACS Catalysis 2014, 4, 3002−3012 - doi: 10.1021/cs500655x
- «Low melting mixtures based on β-cyclodextrin derivatives and N,N’-dimethylurea as solvents for sustainable catalytic processes»
F. Jerome, M. Ferreira, H. Bricout, S. Menuel, E. Monflier, S. Tilloy
Green Chem., 2014, 16 (8), 3876 - 3880 - doi: 10.1039/C4GC00591K
- «Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis»
F. Hapiot, H. Bricout, S. Menuel, S. Tilloy, E. Monflier
Catal. Sci. Technol., 2014, 4, 1899-1908 - doi: 10.1039/C4CY00005F
Selected publications :
- «Functionalized Cyclodextrins as First and Second Coordination Sphere Ligands for Aqueous Organometallic Catalysis»
F. Hapiot, H. Bricout, S. Tilloy, E. Monflier
Eur. J. Inorg. Chem. 2012, 1571–1578 - doi: 10.1002/ejic.201101316
- «Cyclodextrin/Amphiphilic Phosphane Mixed Systems and their Applications in Aqueous Organometallic Catalysis»
M. Ferreira, H. Bricout, N. Azaroual, D. Landy, S. Tilloy, Fr. Hapiot, E. Monflier
Adv. Synth. Catal. 2012, 354, 1337-1346 - doi: 10.1002/adsc.201100837
- «Phosphane-based cyclodextrins as mass transfer agents and ligands for aqueous organometallic catalysis»
S. Tilloy, C. Binkowski-Machut, S. Menuel, H. Bricout, E. Monflier Molecules 2012, 17, 13062-13072 - doi: 10.3390/molecules171113062
- «Synthesis, Rhodium Complexes and Catalytic Applications of a New Water-Soluble Triphenylphosphane-Modified b-Cyclodextrin»
F.X. Legrand, N. Six, C. Slomianny, H. Bricout, S. Tilloy, E. Monflier
Adv. Synth. Catal. 2011, 353, 1325 – 1334 - doi: 10.1002/adsc.201000917
- «Properties and Catalytic Activities of New Easily-Made Amphiphilic Phosphanes for Aqueous Organometallic Catalysis»
M. Ferreira, H. Bricout, N. Azaroual, C. Gaillard, D. Landy, S. Tilloy, E. Monflier Adv. Synth. Catal. 2010, 352, 1193-1203 -
- «Amphiphilic photo-isomerizable phosphanes for aqueous organometallic catalysis»
H. Bricout, E. Banaszak, C. Len, F. Hapiot, E. Monflier
Chem. Commun. 2010, 46, 7813-7815 - doi : 10.1039/C0CC02458A -
- «Ditopic cyclodextrin-based receptors: New perspectives in aqueous organometallic catalysis»
N. Six, S. Menuel, H. Bricout, F. Hapiot, E. Monflier
Adv. Synth. Catal. 2010, 352, 1467-1475 - doi : 10.1002/adsc.201000027 -
- «Cyclodextrins as mass transfer additives in aqueous organometallic catalysis»
H. Bricout, F. Hapiot, A. Ponchel, S. Tilloy, E. Monflier
Curr Org Chem, 2010, 14 (13), 1296-1307
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